Phosphate removal from water by naturally occurring shale,sandstone, and laterite: The role of iron oxides and of soluble species     

Dan Eude Kpannieu  Martine Mallet  Lacina Coulibaly  Mustapha Abdelmoula  Christian Ruby 《Comptes Rendus Geoscience》2019,351(1):37-47

Aqueous phosphate removal by three geomaterials from Ivory Coast was evaluated to determine their potential application as low-cost phosphate adsorbents in wastewater treatment. Batch experiments showed that phosphate uptake strongly depended on pH. Laterite and sandstone dissolution was less pronounced compared to shale. A correlation between concentrations of aqueous cation species released from shale and phosphate uptake was observed. The kinetics were well described using the pseudo-second-order model. Isotherms displayed a saturation level on shale, while phosphate uptake continuously increased for laterite and sandstone. The removal efficiency decreased in the following ranking order: laterite > sandstone > shale. Laterite was also the most efficient adsorbent in column experiments. The high phosphate removal efficiency of laterite (8.3 mg PO₄ g^?1) was attributed to the presence of superparamagnetic low grain sizes of goethite. Laterite is a particularly promising material for further investigation in wastewater treatment technology such as constructed wetlands.  相似文献   

A Review of Study on Fe-C Interaction and Their Adsorption Properties to Soil Heavy Metal     

Zhao Zhuanjun  Yang Yanyan  Pang Yu  Zhao Lifang  Guan Yuli  Zhang Zhaohu 《地球科学进展》2017,32(8):867-874

Nowadays, the Fe-C coprecipitate mechanism is recognized by more and more scholars and becomes the hot topic in the environmental science. On the basis of discussing the interaction between iron oxide and organic matter, and the adsorption research progress of Fe-C complexes on heavy metals, the immobilization potential of Fe-C complexes on heavy metals in polluted soil were illustrated. The surface properties and physical characterizations of iron oxide are changed regularly with the interaction of organic matter, which lead to the higher adsorption capacity of Fe-C complexes in contrast to single iron oxide. Besides, the influences of pH values, organic matter types and surface properties of iron oxides on the adsorption capacity of Fe-C complexes on heavy metals were discussed. The excellent adsorption performance of Fe-C complexes in certain conditions will provide important theoretical basis for contaminated soil remediation.  相似文献   

大别山东南缘侏罗系磨山组沉积环境及地质意义     

张妍  石永红  宋传中  李加好  任升莲  朱琳  冯启  杨帆 《岩石学报》2017,33(2):639-652

侏罗纪是大别造山带与周缘盆地盆山关系研究的一个重要时期,分布在大别造山带周缘的侏罗纪地层为大别山的造山过程以及深俯冲岩石的折返、剥蚀提供了很好的约束。本文选取大别造山带东南缘安庆月山地区侏罗系磨山组为研究对象,对磨山组碎屑岩进行了详细的粒度分析、碎屑组分分析、重矿物分析和碎屑锆石年代学分析。碎屑岩岩石、沉积特征和粒度分析都指示早侏罗世磨山组为三角洲前缘水下分流河道沉积。碎屑组分分析、重矿物分析结合碎屑锆石年代学分析指示磨山组碎屑岩物源主要来自南侧的华南板块,大别造山带宿松杂岩可能为其提供了少量物源,但碎屑物源中未见石榴子石和典型的三叠纪变质锆石,说明此时大别高压-超高压榴辉岩可能仍未折返至地表。  相似文献   

宁芜盆地钟姑矿田典型铁矿成矿岩体Hf-O同位素特征及地质意义   总被引：2，自引：2，他引：0  

孙维安  袁峰  邓宇峰  刘光贤  杨迪  李现锁  傅斌 《岩石学报》2017,33(11):3559-3580

钟姑矿田位于宁芜盆地南部,受矿田内格状构造控制产出一系列早白垩世(129~132Ma)闪长岩及二长岩类侵入体,与铁矿床的形成密切相关,而区域内成矿岩体的研究尤其是岩浆岩的起源和演化有待进一步探讨。本次工作以矿田内的姑山辉石闪长玢岩、龙山辉石闪长岩、白象山闪长岩、钟九闪长岩和太平山二长岩等与铁成矿有关的岩体为研究对象,开展LA-ICP-MS原位锆石Hf同位素和SHRIMP原位O同位素研究。结果显示,钟姑矿田各成矿岩体具有较一致的锆石Hf-O同位素组成,~(176)Hf/~(177)Hf值为0.282425~0.282695,εHf(t)值为-12.3~-3.9,tDM2范围在1.26~1.86Ga;锆石δ18O集中于3.34‰~8.05‰,捕获锆石的176Hf/177Hf比值为0.282324~0.282487,εHf(t)=-15.8~-10.1,锆石tDM2年龄在1.72~20.8Ga之间,锆石δ~(18)O相对集中于5.90‰~6.51‰。钟姑矿田岩浆岩起源于富集的岩石圈地幔,同位素特征指示其携带板块俯冲和蚀变洋壳信息,钟姑矿田的成岩成矿作用应与伸展背景下古太平洋板块俯冲有关。与长江中下游其他矿集区岩浆岩对比研究表明,包括宁芜在内的长江中下游地区岩浆岩具有相同的地幔源区,以铁矿床为主的宁芜和庐枞盆地岩浆岩源区成分以交代岩石圈地幔为主,而以铜陵、繁昌为代表的铜多金属成矿区的岩浆岩受长江中下游新元古代基底的更多影响。  相似文献   

广西清明山铜镍硫化物矿床上升气流微粒研究     

李映葵  曹建劲  陈杰  易杰 《岩石学报》2017,33(3):831-842

为探讨上升气流微粒与深部隐伏矿体之间关系,在广西清明山铜镍硫化物矿床上方土壤中采集上升气流微粒,并采用透射电子显微镜(TEM)对微粒的形貌、大小、聚合状态、化学组分及结构等进行分析。结果表明,微粒主要由Cu、Co、Zn、Fe、Ca、Si、S等元素组成,其中成矿元素Cu、Co以自然Cu-Fe-Co、Zn-Fe-Co及Fe-Co合金微粒的形式存在,其余如Fe、Ca、Si、S等元素则以氢氧化物、氧化物及碳酸盐微粒形式存在。微粒可分为微粒聚合体及单个微粒,微粒的大小为50~500nm,微粒的形状多为不规则状、近椭圆形、近球状、水滴状和近长方体等。微粒中高含量的Cu、Co、Zn来源于深部隐伏矿体,含Fe、S微粒来源于矿床中金属硫化物矿物。此外,高价态的微粒组分指示微粒处于相对氧化的环境。清明山铜镍硫化物矿床的上升气流微粒组分与矿床矿物组分间存在着较好的对应性,本研究为隐伏铜镍硫化物矿床提供了新的找矿方法。  相似文献   

Relative contribution of magmatic and post-magmatic processes in the genesis of the Thompson Mine Ni-Co sulfide ores,Manitoba, Canada     

《Ore Geology Reviews》2017

The Ni-Co-(PGE) sulfide deposits of the Thompson Nickel Belt (TNB) in Northern Manitoba, Canada are part of the fifth largest nickel camp in the world based on contained nickel; past production from the TNB deposits is 2500 kt Ni. The Thompson Deposit is located on the eastern and southern flanks of the Thompson Dome structure, which is a re-folded nappe structure formed during collision of the Trans-Hudson Orogen with the Canadian Shield at 1.9–1.7 Ga. The Thompson Deposit is almost entirely hosted by P2 member sulfidic metasedimentary rocks of the Paleoproterozoic Ospwagan Group. Variably serpentinised and altered dunites, peridotites and pyroxenites contain disseminated sulfides and have a spatial association with sediment-hosted Ni sulfides which comprise the bulk of the ore types. These rocks formed from rift-related komatiitic magmas that were emplaced at 1.88 Ga, and subsequently deformed by boudinage, thinning, folding, and stacking.Disseminated sulfide mineralization in the large serpentinised peridotite and dunite intrusions that host the Birchtree and Pipe Ni-Co sulfide deposits typically has 4–6 wt% Ni in 100% sulfide. The disseminated sulfides in the less abundant and much smaller boudinaged serpentinised peridotite and dunite bodies associated with the Thompson Deposit have 7–10 wt% Ni in 100% sulfide. The majority of Thompson Mine sulfides are hosted in the P2 member of the Pipe Formation which is a sulfidic schist developed from a shale prololith; the mineralization in the schist includes both low Ni tenor (<1 wt% Ni in sulfide) and barren sulfide (<200 ppm Ni) and a Ni-enriched sulfide with 1–18 wt% Ni in 100% sulfide. The semi-massive and massive sulfide ores show a similar range in Ni tenor to the metasediment-hosted mineralization, but there are discrete populations with maximum Ni tenors of ∼8, 11 and 13 wt% Ni in 100% sulfide. The variations in Ni tenor are related to the Ni/Co ratio (high Ni/Co correlates with high Ni tenor sulfide) and this relationship is produced by the different Ni/Co ratios in sulfides with a range in proportions of pyrrhotite and pentlandite. Geological models of the ore deposit, host rocks, and sulfide geochemical data in three dimensions reveal that the Thompson Deposit forms an anastomosing domain on the south and east flanks of a first order D3 structure which is the Thompson Dome. In detail, a series of second order doubly-plunging folds on the eastern and southern flank control the geometry of the mineral zones. The position of these folds on the flank of the Thompson Dome is a response to the anisotropy of the host rocks during deformation; ultramafic boudins and layers of massive quartzite in ductile metasedimentary rocks control the geometry of the doubly-plunging F3 structures. The envelope of mineralization is almost entirely contained within the P2 member of the Pipe formation, so the deposit is clearly folded by the first order and second order D3 structures. The sulfides with highest Ni tenor (typically >13 wt% Ni in sulfide) define a systematic trend that mirrors the configuration of the second order doubly-plunging F3 structures on the flanks of the Dome. Although moderate to high Ni tenor mineralization is sometimes localized in fold hinges, more typically the highest Ni tenor mineralization is located on the flanks of the fold structures.There is no indication of the mineralogical and geochemical signatures of sedimentary exhalative or hydrothermal processes in the genesis of the Thompson ores. The primary origin of the mineralization is undoubtedly magmatic and this was a critical stage in the development of economic mineralization. Variations in metal tenor in disseminated sulfides contained in ultramafic rock indicate a higher magma/sulfide ratio in the Thompson parental magma relative to Birchtree and Pipe. The variation in Ni tenor of the semi-massive and massive sulfide broadly supports this conclusion, but the variations in metal tenor in the Thompson ores was likely created partly during deformation. The sequence of rocks was modified by burial and loading of the crust (D2 events) to a peak temperature of 750 °C and pressure of 7.5 kbar. The third major phase of deformation (D3) was a sinistral transpression (D3 event) which generated the dome and basin configuration of the TNB. These conditions allowed for progressive deformation and reformation of pyrrhotite and pentlandite into monosulfide solid solution as pressure and temperature increased; this process is termed sulfide kinesis. Separation of the ductile monosulfide solid solution from granular pentlandite would result in an effective separation of Ni during metamorphism, and the monosulfide solid solution would likely be spread out in the stratigraphy to form a broad halo around the main deposit to produce the low Ni tenor sulfide. Reformation of pentlandite and pyrrhotite after the peak D2 event would explain the broad footprint of the mineral system. The effect of the D3 event at lower pressure and temperature would have been to locally redistribute, deform, and repeat the lenses of sulfide.The understanding of the relationships between petrology, stratigraphy, structure, and geochemistry has assisted in formulating a predictive exploration model that has triggered new discoveries to the north and south of the mine, and provides a framework for understanding ore genesis in deformed terrains and the future exploration of the Thompson Nickel Belt.  相似文献   

Flood effects on phosphorus immobilisation in a river water filled pit lake—Case study Lake Goitsche (Germany)     

Peter Herzsprung  Martin Schultze  Bertram Boehrer  Anja Duffek  Andrea Van der Veen  Kurt Friese 《Limnologica》2010,40(2):182-190

Between 1999 and 2002, a former open-cast mine was filled with river water forming the recent Lake Goitsche. During filling initially acid water was neutralised. Phosphorus (P) imported from Mulde River was nearly completely removed from the water column by co-precipitation with iron (Fe) and aluminium (Al) and deposited in the sediment.During extremely high waters of the Mulde River in 2002, a dike breach facilitated a second high import of P into Lake Goitsche with suspended and dissolved matter. The analysis of total phosphorus (TP), however, showed that P again had been eliminated from the water body a few months after the flood event. Sediment investigations before filling with river water, during filling, and after the flood event were used to analyse the process of P immobilisation in a lake with acid mine drainage history.The ratios of Fe to soluble reactive P (SRP) of sediment pore water were up to three orders of magnitudes higher than in natural lakes and can serve as an indicator for potential internal P loading from sediments. The SRP concentrations at the oxic/anoxic boundary were near or below the limit of quantification (< 0.2 μmol/L). Fe and manganese (Mn) redox cycling were responsible for hindering P dissolution from sediment to lake water.Finally it can be stated, that the risk of eutrophication for such a lake seems to be low.  相似文献   

山东莱芜接触交代—热液铁矿矿体形态研究   总被引：1，自引：0，他引：1  

宗信德  贾东亮  刘超  尹承亮  刘纪涛  王建 《山东国土资源》2010,26(11)

在对莱芜接触交代铁矿地质特征研究中发现以往地质报告在矿体连接上存在混乱,使矿体形态失真。为便于今后矿体对比和成矿规律的认识,提出了矿体形态分类原则,并以三分法对矿体形态进行分类。指出矿体产状变化是矿体膨胀收缩、分支复合和尖灭再现的结果。根据矿体形态分类指出了找矿方向。不同的矿体形态反映不同的控矿构造,反映不同的矿体规模,反映不同的成矿岩体形态产状。单斜缓倾矿体的成矿岩体是岩床,控矿较小;陡倾矿体和背向斜矿体的成矿岩体是岩盖,控矿较大。  相似文献   

Multi‐Metal‐Substituted‐Goethite as an Effective Catalyst for Azo Dye Wastewater Oxidation          下载免费PDF全文

Sofía Schlichter  Alejandra S. Diez  María C. Zenobi  Mariana Dennehy  Mariana Alvarez 《洁净——土壤、空气、水》2016,44(12):1652-1660

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Preindustrial, historical, and fertilization simulations using a global ocean carbon model with new parameterizations of iron limitation, calcification, and N₂ fixation     

Konstantin Zahariev  James R. Christian  Kenneth L. Denman 《Progress in Oceanography》2008,77(1):56-82

The Canadian Model of Ocean Carbon (CMOC) has been developed as part of a global coupled climate carbon model. In a stand-alone integration to preindustrial equilibrium, the model ecosystem and global ocean carbon cycle are in general agreement with estimates based on observations. CMOC reproduces global mean estimates and spatial distributions of various indicators of the strength of the biological pump; the spatial distribution of the air-sea exchange of CO₂ is consistent with present-day estimates. Agreement with the observed distribution of alkalinity is good, consistent with recent estimates of the mean rain ratio that are lower than historic estimates, and with calcification occurring primarily in the lower latitudes. With anthropogenic emissions and climate forcing from a 1850-2000 climate model simulation, anthropogenic CO₂ accumulates at a similar rate and with a similar spatial distribution as estimated from observations. A hypothetical scenario for complete elimination of iron limitation generates maximal rates of uptake of atmospheric CO₂ of less than 1 PgC y⁻¹, or about 11% of 2004 industrial emissions. Even a ‘perfect’ future of sustained fertilization would have a minor impact on atmospheric CO₂ growth. In the long term, the onset of fertilization causes the ocean to take up an additional 77 PgC after several thousand years, compared with about 84 PgC thought to have occurred during the transition into the last glacial maximum due to iron fertilization associated with increased dust deposition.  相似文献